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Corrosion resistance evaluation of highly dispersed MgO–MgAl2O4–ZrO2 composite and analysis of its corrosion mechanism: A chromium-free refractory for RH refining kilns

作者:Yi-nan Shen1Yi Xing1Peng Jiang2Yong Li2Wen-dong Xue2Guo-xiang Yin2Xue-qin Hong3

作者單位:1. School of Energy and Environmental Engineering,University of Science and Technology Beijing2. School of Materials Science and Engineering,University of Science and Technology Beijing 3. Liaoning Donghe Advanced Material Co.,Ltd.

刊名:International Journal of Minerals Metallurgy and Materials

ISSN:1674-4799

出版年:2019-08-13

卷:26

期:8

起頁:1038-1046

止頁:

分類號:TQ175.7;TF341

語種:英文

關鍵詞:

內容簡介

The corrosion resistance behavior of a highly dispersed MgO–MgAl2O4–ZrO2 composite refractory material is examined by testing with high-basicity and low-basicity RH(Ruhrstahl-Hereaeus) slags.The composite material exhibits greater resistance to the RH slags than the traditional MgO–Cr2O3 composite, MgO–ZrO2 composite, and MgO–MgAl2O4–ZrO2 composite.On the basis of the microstructural analysis and mechanisms calculations, the corrosion resistance behavior of the MgO–MgAl2O4–ZrO2 composite is attributable to its highly dispersed structure, which helps protect the high activity of ZrO2.When in contact with the slag, ZrO2 reacts with CaO to form the stable phase CaZrO3, which protects MgAl2O4 against corrosion, thereby enhancing the corrosion resistance of the composite.

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